Description
Perkadox L-W75 is dibenzoyl peroxide (BPO, CAS 94-36-0) supplied as a white granular powder with 75 % peroxide and 25 % water, from Nouryon. The water phlegmatizes the peroxide, which makes it safer to handle and store than dry benzoyl peroxide while keeping the reactivity of BPO.
In thermoset composites, Perkadox L-W75 cures unsaturated polyester, vinyl ester and acrylic resins at ambient or slightly elevated temperature, usually together with a tertiary amine accelerator. Chemical anchors and mine bolts are typical uses. For cobalt-accelerated room-temperature curing, MEKP grades such as Butanox M-50 are the usual alternative. In polymer production it initiates styrene polymerization at 80–100 °C and acrylate polymerization at 65–100 °C. The bifunctional Trigonox 141 offers activity comparable to Perkadox L-W75 with higher polymer molecular weight, and Trigonox C covers the higher 100–140 °C range of styrene polymerization. See all grades in the organic peroxide range.
Perkadox L-W75 key data
| Property | Value |
| Chemical name | Dibenzoyl peroxide (BPO), 75 % with water |
| CAS number | 94-36-0 |
| EINECS / ELINCS | 202-327-6 |
| Appearance | White granular powder |
| Assay | 74.0–76.0 % |
| Water content | About 25 % |
| Active oxygen | 4.88–5.02 % |
| Bulk density | 630 kg/m³ |
| Half-life temperature, 10 h / 1 h / 0.1 h (chlorobenzene) | 71 °C / 91 °C / 113 °C |
| Activation energy | 122.35 kJ/mol |
| SADT | 70 °C |
| Maximum storage temperature (Ts max) | 40 °C |
| Transport classification | Organic peroxide type C, solid; Division 5.2; UN 3104 |
| Standard packaging | Cardboard box with 4 × 6.7 kg PE bags |
| Shelf life | At least 3 months after delivery when stored as recommended |
Perkadox L-W75 TDS & SDS download
The Perkadox L-W75 product data sheet (TDS/PDS) lists specifications, half-life data and storage limits. The safety data sheet (SDS/MSDS) covers hazard classification, transport and emergency measures. Both English documents can be downloaded below. Data sheets for polymer production and thermoset composites, and Chinese versions, are available on request.
Applications
- Chemical anchors and mine bolts: ambient cure of unsaturated polyester, vinyl ester and methacrylate resins with a tertiary amine accelerator.
- Thermoset composites: cure of UP, VE and acrylic resins at ambient or slightly elevated temperature.
- Polystyrene: initiator for styrene polymerization at 80–100 °C.
- Acrylics: bulk and suspension polymerization and copolymerization of acrylates and methacrylates at 65–100 °C.
- Other monomers: polymerization and copolymerization of vinyl acetate, (meth)acrylonitrile, tetrafluoroethylene, divinylbenzene, para-methylstyrene and diallyl phthalate.
Storage and handling
Store Perkadox L-W75 below 40 °C in tightly closed original packaging, in a dry, well-ventilated area away from heat, ignition sources and direct sunlight. Keep it away from reducing agents such as amines, acids, alkalis and heavy metal compounds. Keep the product moist: the water content is part of its safety formulation. It is shipped as organic peroxide type C, solid (UN 3104).
Perkadox L-W75 FAQ
Q: What is Perkadox L-W75?
A: Perkadox L-W75 is Nouryon's dibenzoyl peroxide (BPO), CAS 94-36-0, supplied as a white granular powder with 75 % peroxide and 25 % water. It is used to cure UP, vinyl ester and acrylic resins and to initiate styrene and acrylate polymerization.
Q:
Why does Perkadox L-W75 contain 25 % water?
A:
The water phlegmatizes the benzoyl peroxide, which reduces its sensitivity and makes it safer to handle, store and transport than dry BPO.
Q:
How is Perkadox L-W75 used to cure polyester resin?
A:
It cures unsaturated polyester, vinyl ester and acrylic resins at ambient or slightly elevated temperature, usually combined with a tertiary amine accelerator. Chemical anchors and mine bolts are typical applications.
Q:
What is the half-life temperature of Perkadox L-W75?
A:
Measured in chlorobenzene, its 10-hour half-life temperature is 71 °C, its 1-hour half-life temperature is 91 °C and its 0.1-hour half-life temperature is 113 °C. Its SADT is 70 °C.
Q:
How should Perkadox L-W75 be stored?
A:
Store it below 40 °C in closed original packaging, away from heat, sunlight, amines, acids, alkalis and heavy metal compounds. Under these conditions it stays within specification for at least 3 months after delivery.
Q:
Where can I get the Perkadox L-W75 TDS and SDS?
A:
The English product data sheet and safety data sheet can be downloaded on this page. Send an inquiry for application-specific data sheets or Chinese versions.

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